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  5. α-Amylase and α-glucosidase inhibitors from Zanthoxylum chalybeum Engl. root bark.

α-Amylase and α-glucosidase inhibitors from Zanthoxylum chalybeum Engl. root bark.

Resource type
Journal article
Creator (person)
Ochieng, Charles O.
Nyongesa, Daniel W.
Yamo, Kevin O.
Onyango, Joab O.
ORCIDORCID logo
Langat, Moses K.
ORCIDORCID logo
Manguro, Lawrence A. O.
Date published
October 2020
Abstract
A systematic analysis of the root bark of Zanthoxylum chalybeum was conducted to establish the antidiabetic potential of isolated compounds based on its ethnomedicinal use to manage diabetes. Chromatographic separation of alkaloid extracts led to isolation of three undescribed amides, chaylbemide A (1), chalybemide B (2) and chalybemide C (3) alongside the known fagaramide (4); four known benzophenanthridine alkaloids skimmianine (5), norchelerythrine (6), 6-acetonyldihydrochelerythrine (7) and 6-hydroxy-N-methyl decarine (8). The alkaloid free extracts yielded three known lignans, ailanthoidol (9), 2,3-epoxy-6,7-methylenedioxy coniferyl alcohol (10), sesamine (11), together with five known triterpenoids, lupeol (12), lupanone (13), 3α,20-dihydroxy-28-lupanoic acid (14), 20-hydroxy-3-oxo-28-lupanoic acid (15) and 3α,20,28-trihydroxylupane (16). The structures of the compounds were established based on 1D and 2D NMR spectroscopic and mass spectrometric experiments. Compounds 1–8 displayed inhibitory activities against both α-amylase and α-glycosidase in the range of IC50 = 43.22–49.36 μM which showed no significant (P > 0.05) difference to the positive control acarbose (IC50 = 42.67; 44.88 μM). The results confirmed anti-hyperglycemic potential of alkaloids from Z. chalybeum which lends credence to its use towards management of diabetes susceptibilities.
Funder
Funder nameAwards
Third World Academy of Science TWAS
RGA NO. 18-192 RG/CHE/AF/AC_G_FR3240303660
Journal title
Fitoterapia
Volume
146
Publisher
Elsevier BV
Place of publication
Amsterdam, Netherlands
ISSN
0367-326X
eISSN
1873-6971
Date accepted
August 30, 2020
Official URL
http://dx.doi.org/10.1016/j.fitote.2020.104719
Rights statement
In Copyright
DOI
10.1016/j.fitote.2020.104719
Keywords
Antidiabetic
Zanthoxylum chalybeum
α-Amylase and α-glucosidase inhibitors
Amide alkaloids
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